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Organic Letters, 2011, 13(21), 5904-5907. |
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Master  |
2011-10-12 10:02:03, VIEW : 3,515 |
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Encapsulation of Anionic guests in a New Hydantoinylamido Molecular Capsule
Yeon Sil Park,¢Ó Sungjong Seo,¢Ó Eun-Hee Kim,¢Ô and Kyungsoo Paek*,¢Ó
Resorcin[4]arene-based tetrakis(N-hydantoinylamido)cavitand 1 forms a stable molecular capsule in the presence of suitable anionic guests such as CH3OSO3 or BF4 in C2D2Cl4.
Molecular capsule G2@12 is stabilized by the eight intermolecular imide N-H 3 3 3 OdC hydrogen bondings, two from each four paired hydantoinyl units, and the eight intramolecular amide N-H 3 3 3 OCH2-O hydrogen bondings, four on each two cavitands.
The formations of molecular capsules were confirmed by 1H, 2D NOESY, and 2D-DOSY NMR. |
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2847 |
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±¹Á¦Çмú | Organic Letters, 2011, 13(21), 5904-5907. |
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3515 |
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