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Tetrahedron Letters, 2017, 58, 3366-3369. |
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2017-08-01 09:42:07, VIEW : 633 |
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Molecular capsules of tetrakis(N-hydantoinylimino)cavitand: Selective
encapsulation of 1,4-diiodobenzene
Yeon Sil Park, Jo Won Kim, Kyungsoo Paek
Resorcin[4]arene-based iminocavitand 2 with four hydantoinyl moieties was designed and synthesized.
This cavitand 2 self-assembled into thermally stable molecular capsules G@22 in the presence of suitable
guests through 8 intermolecular hydrogen bonds of imide NAHO@C, two for each four paired hydantoinylunits. Molecular capsule 22 showed selective complexation for p-disubstituted benzenes, especially for 1,4-diiodobenzene. |
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