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Organic Letters 2019, 21(20), 8300-8303. |
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2019-11-06 12:55:24, VIEW : 155 |
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Organic Letters 2019, 21(20), 8300-8303.
Specific Encapsulation of Acetylcholine Chloride by a Self-Assembled Molecular Capsule with Sulfonamido Moiety
Yeon Sil Park*, Yangryeong Kim, Kyungsoo Paek*
Abstract
New molecular capsule 12, which encapsulates only acetylcholine chloride in the ion-pair form, has been developed. Cavitand 1 with four sulfonamido moieties on the upper rim of tetraimino-cavitand self-assembled to form a stable molecular capsule in the presence of an acetylcholine chloride guest through eight intermolecular —NH···O═S hydrogen bonds, two from each of the four paired sulfonamide units. |
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